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lead titanate : ウィキペディア英語版
lead titanate

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Lead(II) titanate is an inorganic compound with the chemical formula PbTiO3. It is the lead salt of titanic acid and has a high ratio of k33 to kp with a high kt. Lead(II) titanate is a yellow powder that is insoluble in water.
At high temperatures, lead titanate adopts a cubic perovskite structure. At 760 K,〔Noheda, Cereceda, Iglesias, Lifante, Gonzalo, Chen and Wang, Phys. Rev. B 51, 16388 (1995)〕 the material undergoes a second order phase transition to a tetragonal perovskite structure which exhibits ferroelectricity. Lead titanate is one of the end members of the lead zirconate titanate (Pb() 0≤''x''≤1, PZT) system, which is technologically one of the most important ferroelectric and piezoelectric ceramics.
Lead titanate occurs in nature as mineral macedonite.〔Radusinović, Dušan and Markov, Cvetko "Macedonite - lead titanate: a new mineral", ''American Mineralogist'' 56, 387-394 (1971), http://www.minsocam.org/ammin/AM56/AM56_387.pdf〕〔Burke, E.A.J. and Kieft, C. "Second occurrence of makedonite, PbTiO3, Långban, Sweden", ''Lithos'' 4, 101-104 (1971)〕
==Toxicity==
Lead titanate is toxic, like other lead compounds. It irritates skin, mucous membranes and eyes. It may also cause harm to unborn babies and might have effects on fertility.〔http://www.alfa.com/content/msds/USA/35671.pdf〕

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